Journal
TETRAHEDRON
Volume 60, Issue 39, Pages 8645-8657Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.05.109
Keywords
polymer-supported; N-hydroxyphthalimide; alkoxyamine; stereochemical diversity; positional diversity
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The synthesis of a polymer-supported N-hydroxyphthalimide is described. The polystyrene-bound N-hydroxyphthalimide resin 1 has been used to prepare complex alkoxyamines exhibiting both stereochemical and positional diversity. Methods for efficient condensation of complex alkoxyamines with aldehydes and ketones are also outlined. (C) 2004 Elsevier Ltd. All rights reserved.
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