Journal
APPLIED CATALYSIS A-GENERAL
Volume 272, Issue 1-2, Pages 109-114Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2004.05.020
Keywords
verbenol synthesis; alpha-pinene oxidation; verbenyl-hydroperoxide hydrogenation on Pd/C; kinetics; mechanism
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Kinetic peculiarities of alpha-pinene liquid-phase oxidation by molecular oxygen were studied (in a temperature range of 343-393 K and at oxygen pressure within 0.5-6 bar range). The process proceeds selectively at a low alpha-pinene conversion and the main products are verbenyl-hydroperoxide and alpha-pinene epoxide. The products ratio depends slightly on temperature, oxygen pressure and alpha-pinene conversion. The kinetic equation for the reaction rate was suggested. (C) 2004 Elsevier B.V. All rights reserved.
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