Journal
ORGANIC LETTERS
Volume 6, Issue 20, Pages 3477-3480Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol048759t
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An efficient one-pot sequence comprising a homolytic aromatic substitution followed by an ionic Horner-Wadsworth-Emmons olefination for the preparation of a small library of alpha,beta-unsaturated oxindoles is presented. Microwave-induced heating is used to conduct these reactions. The homolytic aromatic substitution is mediated by the persistent radical effect.
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