Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 12, Pages 1449-1456Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404104
Keywords
biphasic catalysis; cyclodextrins; molecular recognition; palladium; phosphane ligands
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Formation of stable second-sphere adducts between a water-soluble organometallic complex and a cyclodextrin (CD) is possible by finely designing the structure of the water-soluble phosphane. The key point to obtain such adducts was the synthesis of a water-soluble phosphane which possesses a tert-butylphenyl group recognized by the CD and separated from the phosphorus atom by a phenyl ring to avoid phosphane decoordination during the molecular recognition process between the organometallic complex and the CD. These adducts are able to catalyze the cleavage of water-insoluble carbonate in a biphasic system.
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