Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 12, Pages 1435-1439Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404166
Keywords
asymmetric synthesis; Mannich reaction; organic catalysis; oxidation; proline
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trans-4-tert-Butyldimethylsiloxy-L-proline displays a greater catalytic activity than the parent proline without compromising the enantioselectivity, which widens the substrate scope in the alpha-aminoxylation of carbonyl compounds, as well as O-nitrosoaldol/Michael, and Mannich reactions.
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