Journal
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume 51, Issue 5B, Pages 1193-1200Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.200400175
Keywords
L-hexose; 1,6-anhydro-beta-L-hexopyranoses; bleomycin A(2); heparin
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This account describes our recent work in the development of new methodologies to prepare rare and biologically potent L-hexoses and 6-deoxy-L-hexoses, from cheapest D-glucose, via L-hexofuranoses and 1,6-anhydro-beta-L-hexopyranoses as key building blocks. Their applications in the syntheses of heparin oligosaccharides, the carbohydrate moiety of bleomycin A(2), and L-acovenose are also summarized here.
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