A novel layered Li[Li0.12NizMg0.32-zMn0.56]O2 cathode material for lithium-ion batteries

Layered Li[Li0.12NizMg0.32-zMn0.56]O-2 oxide cathodes containing lithium atoms in the transition metal layers were synthesized and characterized using X-ray diffraction (XRD), galvanostatic cycling, and differential scanning calorimetry (DSC). The Li[Li0.12NizMg0.32-zMn0.56]O-2 cathodes deliver a specific discharge capacity of about 190 mAh/g at room temperature and 236 mAh/g at 55 degreesC when cycled between 2.7 and 4.6 V versus Li/Li+. Excellent capacity retention and smooth potential profiles at room and elevated temperatures over extended cycles suggest that this material does not convert into a spinel structure. (C) 2004 Elsevier Ltd. All rights reserved.