Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 12, Pages 1429-1434Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404048
Keywords
alkenes; N-heterocyclic carbenes; homogeneous catalysis; hydrosilylation; platinum
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Readily available N-heterocyclic platinum-carbene complexes 1 are highly efficient catalysts for the regioselective hydrosilylation of alkenes. These novel organometallics tolerate a wide range of functional and protecting groups, can be stored for prolonged periods of time and are particularly active (TON > 10(6)).
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