4.3 Article

Mild oxidative bromination of alkenes and alkynes with zinc bromide and lead tetraacetate

Journal

SYNTHETIC COMMUNICATIONS
Volume 34, Issue 19, Pages 3545-3552

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1081/SCC-200031007

Keywords

bromination; alkenes; alkynes; zinc bromide; lead tetraacetate

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Zinc bromide and lead tetraacetate is a practical and safe source of bromine. The combined reagents are used to brominate a variety of alkenes to vicinal dibromoalkanes. Similarly, alkynes can be converted into dibromoalkenes in high yields. The reagents are also capable of tetrabromination of alkynes.

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