4.6 Article

Nonpolar resistive switching in Mn-doped BiFeO3 thin films by chemical solution deposition

Journal

APPLIED PHYSICS LETTERS
Volume 101, Issue 6, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.4742897

Keywords

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Funding

  1. NSFC [10902128, 10732100, 50802026, 10972239]
  2. New Century Excellent Talents in University
  3. Fundamental Research Funds for the Central Universities
  4. Research Fund for the Doctoral Program of Higher Education
  5. Fok Ying Tung Foundation

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Nanoscale Mn-doped BiFeO3 (BFMO) films are prepared by chemical solution deposition on Pt/Ti/SiO2/Si substrates. Nonpolar nonvolatile resistive switching has been observed in Pt/BFMO/Pt structure. Analysis of the current-voltage relationship demonstrates that the space-charge-limited current conduction controlled by the localized traps should be of great importance to the resistance switching. X-ray photoelectron spectroscopy results suggest that the coexistence of Fe2+ and Fe3+ can be ascribed to the relatively oxygen vacancies. According to defect chemistry, the valence variation between Fe2+ and Fe3+ determined by the neutralization/ionization of oxygen vacancies is supposed to play a crucial role in conductive filament-related nonpolar resistive switching. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4742897]

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