Journal
APPLIED PHYSICS LETTERS
Volume 101, Issue 21, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4767999
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Functional plasma polymers were deposited from pure ethylene discharges and with the addition of carbon dioxide or ammonia. The incorporation of oxygen and nitrogen-containing functional groups depends on the fragmentation in the gas phase as well as on the densification during film growth. While a minimum energy per deposited carbon atom is required for cross-linking, the densification and accompanying reduction of functional group incorporation was found to scale linearly with momentum transfer through ion bombardment during film growth. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4767999]
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