4.6 Article

How to fabricate a semihydrogenated graphene sheet? A promising strategy explored

Journal

APPLIED PHYSICS LETTERS
Volume 101, Issue 7, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.4746756

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Funding

  1. National Natural Science Foundation of China [NSFC-21173007]
  2. National Grand Fundamental Research 973 Program of China [2012CB921404]

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There has been a long-standing dream to synthesize a semihydrogenated graphene sheet. Here, we propose a promising strategy based on physical method instead of chemical method to avoid the current problems in synthesizing. By applying pressure on a fluorinated BN sheet supported on a graphene sheet, we can induce a structural transition for H atoms jumping from the graphane sheet to fluorinated BN sheet, thus transforming the graphane sheet to a graphone sheet. Moreover, hole doping can reduce the pressure required for such structural transition. This strategy is more feasible and controllable as compared to the existing experimental techniques. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4746756]

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