Journal
BIOORGANIC CHEMISTRY
Volume 32, Issue 5, Pages 367-375Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.bioorg.2004.05.005
Keywords
enzyme mechanism; alpha beta-hydrolase; C-C hydrolase; haloperoxidase; hydroxynitrile lyase; dioxygenase
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The article describes the observation of novel catalytic activities in the alphabeta-hydrolase superfamily apparently unrelated to ester hydrolysis and unexpected biochemical observations relating to the structure and function of the serine catalytic triad in these enzymes. One common feature of these novel activities is the activation of a small diatomic molecule, but via diverse chemistry. Possible mechanisms of catalysis are discussed. (C) 2004 Elsevier Inc. All rights reserved.
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