Journal
INORGANIC CHEMISTRY
Volume 43, Issue 20, Pages 6139-6141Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic0496166
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Reversible construction of a nanoporous framework from a nonporous framework has been found in the zinc(II) coordination polymer with 4,4'-oxybis(benzoate) (oba). [Zn-2(oba)(2)(dmf)(2)](.)2DMF (1), which has 1 nm scale channels, transforms to the nonporous coordination polymer [Zn(oba)(H2O)] (2) with the loss of the open framework. Compound 2 on treatment with DMF reversibly yields nanoporous compound 1.
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