4.4 Article

Application of an air stable Pd oxazoline complex for Heck, Suzuki, Sonogashira and related C-C bond-forming reactions

Journal

TETRAHEDRON LETTERS
Volume 45, Issue 41, Pages 7689-7691

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.08.082

Keywords

C-C bond formation; palladium; Heck; Sonogashira; Suzuki; catalysis; oxazoline

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The novel complex trans-[PdCl2(eta(1)-N-2-ethyl-2-oxazoline)(2)] is shown to be an active and oxidatively robust catalyst for C-C bond-forming reactions (Heck, Sonogashira, Ullman, Suzuki), which can be carried out in air without rigorous solvent/substrate purification and in the absence of additional free ligand. (C) 2004 Elsevier Ltd. All rights reserved.

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