Journal
DESALINATION
Volume 169, Issue 3, Pages 269-275Publisher
ELSEVIER
DOI: 10.1016/j.desal.2003.11.007
Keywords
Ti4O7; anatase; hydrolysis; photocatalysis; carbon-coating; EXAFS
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Fine particles of photocatalytic anatase TiO2 prepared through hydrolysis of titanium tetraisopropoxide were coated by carbon. A reduced phase, Ti4O7 was formed through interaction between TiO2 and the coating carbon. EXAFS analysis on this Ti4O7 phase showed an intermediate Ti-Ti distance between those in anatase and rutile, which agreed with the structure composed of two-dimensional slabs of Ti-O octahedra separated by a shear plane. This carbon-coated Ti4O7 was confirmed to have photocatalytic activity, even though a little lower than anatase, examining the decomposition of methylene blue in water under UV irradiation.
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