4.4 Article

Synthesis of aryl phosphines via phosphination with triphenylphosphine by supported palladium catalysts

Journal

TETRAHEDRON
Volume 60, Issue 42, Pages 9433-9439

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.08.020

Keywords

palladium catalysts; phosphination; aryl halides

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The palladium catalyzed phosphination of functionalized aryl bromides, triflates, and chlorides with triphenylphosphine to yield aryldiphenylphosphines was catalyzed by thermally stable palladium catalysts supported on charcoal and aluminia. The addition of NaI promoted both the rates and yields in the phosphination with Pd/C. (C) 2004 Elsevier Ltd. All rights reserved.

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