Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 69, Issue 21, Pages 7277-7283Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo049275d
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The conjugated delta-lactone passifloricin A, a natural product with antiprotozoal activity, and seven isomers thereof have been synthesized in enantiopure form. It has been shown in this way that the proposed structure for the natural compound was erroneous. The correct structure is now evidenced. Key steps of the syntheses were asymmetric Brown-type aldehyde allylations and ring-closing metatheses.
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