4.7 Article

Silk sericin retards the crystallization of silk fibroin

Journal

MACROMOLECULAR RAPID COMMUNICATIONS
Volume 25, Issue 20, Pages 1792-1796

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200400333

Keywords

crystallization; intermolecular hydrogen bonding; phase separation; silk fibroin; silk sericin

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The thermal and structural analysis of silk fibroin (SF) and silk sericin (SS) blend films reveals that the crystallization of SF is retarded in the presence of SS. Although a phase separation was observed, there might be a strong interaction at the boundary of the SF and SS through intermolecular hydrogen bonding, which restricts the conformational transition of SF.

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