Journal
JOURNAL OF CATALYSIS
Volume 227, Issue 2, Pages 459-469Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2004.08.006
Keywords
ethylbenzene; transalkylation; dealkylation; zeolites; heavy reformate
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A catalyst has been designed to optimize the dealkylation of ethyl and propyl aromatics while producing the transalkylation of tri- and tetramethylbenzene with toluene in order to maximize xylenes and benzene when processing heavy reformate. Conversion of model ethyl-aromatics under realistic transalkylation conditions has been studied over two reference catalysts and seven different acid zeolites including topologies with channel systems containing 10 MR, 12 MR, and 10 + 12 MR. Catalytic testing was accomplished by means of a high-throughput reactor system. It has been found that zeolite structure has a direct influence on the ethyl dealkylation/transalkylation activity, increasing the ethylbenzene conversion and dealkylation selectivity when decreasing the zeolite pore volume. Moreover, Re/IM-5 and, specially. Re/ZSM-5 zeolites show an excellent dealkylation activity. Ethylbenzene undergoes different bimolecular reactions giving as primary products either benzene and diethylbenzene or toluene and ethyltoluene, each reaction involving a different biphenylic intermediate and the selectivity toward each mechanism is directly influenced by the zeolite pore size and geometry. (C) 2004 Elsevier Inc. All rights reserved.
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