Journal
ORGANIC LETTERS
Volume 6, Issue 22, Pages 4073-4076Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol048229x
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Smooth and selective Payne rearrangement was achieved for the above types of epoxyalcohols with a CF3 group so as to form thermodynamically more stable alkoxides, where the strongly electron-withdrawing nature of this moiety played a significantly important role and was proved to overcome increased steric instability of epoxides from syn-E to anti-Z isomers.
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