Journal
ORGANIC LETTERS
Volume 6, Issue 22, Pages 4077-4080Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0482137
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- NIAID NIH HHS [AI 47840, AI 01682, AI 45606] Funding Source: Medline
- NIGMS NIH HHS [GM 60271] Funding Source: Medline
- CCR NIH HHS [RCMI-RR 03037] Funding Source: Medline
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Olefin cross-metathesis has been used to prepare alpha-C-galactosylceramide derivatives. The metathesis process merged vinyl and propenyl glycosides with vinyl derivatives of phytosphingosine. The use of ethylene enhanced the yield of the methathesis step.
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