Journal
ORGANIC LETTERS
Volume 6, Issue 22, Pages 4113-4115Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol048149t
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The combination of catalytic palladium(0) and Trost ligand provides an effective catalyst for the rearrangement of allyl beta-ketoesters. The mechanism of the transformation involves formation of pi-allyl palladium intermediates which undergo enantioselective attack by ketone enolates. Decarboxylation of beta-ketocarboxylates allows regiospecific generation of enolates under extremely mild conditions.
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