Crystallization of charge holes in the spin ladder of Sr14Cu24O41

Determining the nature of the electronic phases that compete with superconductivity in high-transition-temperature (high-T-c) superconductors is one of the deepest problems in condensed matter physics. One candidate is the 'stripe' phase(1-3), in which the charge carriers ( holes) condense into rivers of charge that separate regions of antiferromagnetism. A related but lesser known system is the 'spin ladder', which consists of two coupled chains of magnetic ions forming an array of rungs. A doped ladder can be thought of as a high-T-c material with lower dimensionality, and has been predicted to exhibit both superconductivity(4-6) and an insulating 'hole crystal'(4,7,8) phase in which the carriers are localized through many-body interactions. The competition between the two resembles that believed to operate between stripes and superconductivity in high-T-c materials(9). Here we report the existence of a hole crystal in the doped spin ladder of Sr14Cu24O41 using a resonant X-ray scattering technique(10). This phase exists without a detectable distortion in the structural lattice, indicating that it arises from many-body electronic effects. Our measurements confirm theoretical predictions(4,7,8), and support the picture that proximity to charge ordered states is a general property of superconductivity in copper oxides.