4.7 Article

Diels-Alder additions of benzynes within helicene skeletons

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 69, Issue 22, Pages 7769-7771

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo048707h

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Although the contortions required are unprecedented, the benzynes formed by the fluoride-induced elimination of TMSOTf from o-trimethylsilyl [6]- and [7]-helicenol triflates add to another ring of the helicenes rather than to an external furan molecule.

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