Journal
ELECTROCHIMICA ACTA
Volume 49, Issue 27, Pages 4939-4947Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2004.06.006
Keywords
natural graphite; photoelectron spectroscopy; propylene carbonate; vinylene carbonate; solid electrolyte interphase
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The origin of the different Li+ intercalation behaviour of raw and jet-milled natural graphite has been investigated. Jet-milled graphite is found to cycle reversibly in equal solvent mixture of propylene carbonate (PC) and ethylene carbonate (EC), whereas raw graphite does not. Using both Al Kalpha and synchrotron radiation (SR) Photoelectron Spectroscopy, new insight is obtained into the formation of the solid electrolyte interphase (SEI) on the two different graphite materials during electrochemical cycling in 1 M LiPF6 in either PC:EC (1: 1) or in PC with 5% vinylene carbonate (VC) as additive. Solvent reduction products are found at the surface of both raw and jet-milled graphite cycled in PC:EC (1:1), but differed in composition. The addition of VC reduces primarily the quantities of salt reaction products (LiF and LixPFy compounds) and produces a mainly organic SEI layer. Electron diffraction from the edges for raw and jet-milled graphite particles shows a more disordered surface structure in the jet-milled particles than in the raw graphite. The more disordered surface structure can serve as a physical barrier hindering PC co-intercalation and facilitating the formation of a stable SEI layer. (C) 2004 Elsevier Ltd. All rights reserved.
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