Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 57, Issue 17-18, Pages 1447-1517Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970412331297523
Keywords
synthetic modification of carbohydrates; sugar-metal complexes; supramolecular structures; diastereoselective reactions
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The coordinative properties of synthetically modified carbohydrates to metal cations are reviewed. Such metal complexes are distinct, owing to the structural diversity of the ligands and coordination modes. The influences of complex-formation conditions on chemical properties of modified carbohydrates, as well as on organic reactions (especially diastereoselective ones), are examined. In addition, this manuscript demonstrates the practical importance of the coordination interactions.
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