Journal
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume 60, Issue 13, Pages 3087-3092Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2004.01.031
Keywords
dithiocarbamate complexes; spectral, thermal and in vitro study; triphenyl phosphine
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Triphenyl phosphine adducts of dithiocarbamate complexes of platinum(IV) and palladium(II) of the type [Pt(L)(2)PPh3Cl2] and [Pd(L)(2)PPh3] [L: morpholine dithiocarbarnate (L-1), aniline dithiocarbarnate (L-2) and N-(methyl, cyclohexyl) dithiocarbamate (L-3)] were prepared and characterized by elemental analysis, electronic, IR, H-1 NMR and C-13 NMR spectral studies. Thermal studies of the complexes were carried out. In vitro antitumor activity has been screened towards human adenocarcinoma cell lines and showed significant inhibition even at very low concentration. (C) 2004 Elsevier B.V. All rights reserved.
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