Journal
MARINE CHEMISTRY
Volume 90, Issue 1-4, Pages 107-123Publisher
ELSEVIER
DOI: 10.1016/j.marchem.2004.02.022
Keywords
mercury; methylmercury; estuarine sediments; enriched stable isotopes; methylation; demethylation; volatilization
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Species-specific enriched stable isotopes have been used to study mercury transformations (methylation, demethylation and volatilization) in estuarine sediments under different environmental conditions (both biotic and abiotic and oxic and anoxic). These experiments have demonstrated the potential for the isotopically enriched species in combination with highly sensitive measurement methods (ICP MS) to facilitate the study of mercury speciation and reactivity. Sediments (sterilized and nonsterilized) were spiked with both isotopically enriched inorganic (Hg-199) and monomethylmercury ((MMHg)-Hg-201) at environmental levels to avoid perturbing the system and incubated under both aerobic and anaerobic conditions. The formation of (MMHg)-Hg-199 and the degradation of (MMHg)-Hg-201 were measured simultaneously during time series experiments by capillary gas chromatography-inductively coupled mass spectrometry. Specific methylation and demethylation rate constants (K-m and K-d) were calculated. Results clearly showed that methylmercury levels in sediments are controlled by competing and simultaneous methylation and demethylation reactions. Operating conditions, likely to drastically modify the reactivity of the media, were of primary importance to assess the relative significance of each mechanism. In estuarine sediments, mercury methylation was enhanced under anaerobic nonsterile conditions, whereas other environmental conditions were either less favorable for monomethylmercury production or more effective for its degradation. The production of total gaseous mercury was found to be minimal, although it could be demonstrated that it was related to the fate and transformation of methylmercury. (C) 2004 Elsevier B.V All rights reserved.
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