Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 42, Issue 21, Pages 5548-5558Publisher
WILEY-BLACKWELL
DOI: 10.1002/pola.20396
Keywords
atom transfer radical polymerization (ATRP); kinetics (polym.); living polymerization; radical polymerization
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Kinetic studies of the atom transfer radical polymerization (ATRP) of styrene are reported, with the particular aim of determining radical-radical termination rate coefficients (). The reactions are analyzed using the persistent radical effect (PRE) model. Using this model, average radical-radical termination rate coefficients are evaluated. Under appropriate ATRP catalyst concentrations, values of approximately 2 X 10(8) L mol(-1) s(-1) at 110 degreesC in 50 vol % anisole were determined. (C) 2004 Wiley Periodicals, Inc.
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