Journal
APPLIED PHYSICS LETTERS
Volume 97, Issue 20, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3514255
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Funding
- U.S. DOE, Office of Basic Energy Sciences, and Division of Materials Science and Engineering [DE-FG02-07ER46410]
- Slovenian Research Agency [P1-0125, P2-0105, J1-2015]
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We report the directly measured electrocaloric effect (ECE) (the adiabatic temperature change Delta T) of relaxor ferroelectric poly (vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) terpolymer and its blend with poly (vinylidene fluoride-chlorotrifluoroethylene). The results show that the directly measured Delta T in the relaxor terpolymer is much larger than that deduced from Maxwell relation and that the relaxor terpolymer possesses a giant ECE at room temperature. The large difference between the directly measured Delta T and that deduced indicates that the Maxwell relation, which is derived for ergodic systems, is not suitable for deducing ECE in the relaxor ferroelectric polymers, which are nonergodic (polar-glass) material systems. (C) 2010 American Institute of Physics. [doi:10.1063/1.3514255]
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