Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 69, Issue 23, Pages 8108-8110Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo040218u
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Funding
- NIGMS NIH HHS [S06GM53933-0251] Funding Source: Medline
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A variety of aminoalkynes and related heterocycles are reacted in the Bronsted superacid CF3SO3H (triflic acid), and products are obtained in generally good yields (69-99%) from Friedel-Crafts-type reactions. The reactions are consistent with the formation of novel dicationic intermediates having a vinyl cationic site and an adjacent protonated N-heterocycle or ammonium cation.
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