Journal
TETRAHEDRON LETTERS
Volume 45, Issue 47, Pages 8709-8711Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.09.134
Keywords
carbohydrates; enzyme catalysis; glycosidase
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Two cyclodextrin A,D-diacids were synthesized and found to catalyze the hydrolysis of nitrophenyl glycosides with k(cat)/k(uncat) of up to 35. The hydrolysis followed Michaelis-Menten kinetics, Could be inhibited by compounds binding the cavity, and occurred optimally at pH 7.4. (C) 2004 Published by Elsevier Ltd.
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