Journal
ORGANIC LETTERS
Volume 6, Issue 24, Pages 4495-4498Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol047991w
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1,3-Dipolar synthons formed from vicinal TBDPS-substituted cyclopropyl alkyl/phenyl ketones on treatment with Lewis acids such as TiCl4 and Et2AlCl reacted with allenylsilanes to furnish [3 + 2] and [3 + 3] adducts with high regio- and stereocontrol.
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