Journal
ORGANIC LETTERS
Volume 6, Issue 24, Pages 4543-4546Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol048111g
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Ru-catalyzed [2 + 2] cycloadditions between norbornadiene and alkynyl halides were found to occur in moderate to good yields (32-89%). The presence of the halide moiety greatly enhances the reactivity of the alkyne component in the cycloaddition and can be transformed into a variety of products that are difficult or impossible to obtain via direct cycloaddition.
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