Journal
TETRAHEDRON LETTERS
Volume 45, Issue 49, Pages 8969-8971Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.10.051
Keywords
nucleophilic addition; carbonyl allylation; pi-allylrhodium; tin(II) chloride
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Rhodium complexes such as [RhCl(cod)](2), [Rh(cod)(2)]BF4, and [Rh(cod)(CH3CN)(2)]BF4 function as catalysts for carbonyl allylations by allylic alcohols with 1 equiniolar amount of tin(II) chloride to each allylic alcohol and aldehyde in THF at 50degreesC to produce the corresponding homoallylic alcohols.
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