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JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 689, Issue 24, Pages 4165-4183Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2004.09.012
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This paper reviews progress in the field of thermally stable silylenes since 2000. Developments in the synthesis and characterization of new stable silylenes are discussed, followed by a summary of recent theoretical calculations upon model silylenes. The main part of the article concerns the reactivity patterns displayed by silylenes 1-4, which are discussed in terms of their behavior toward radical, organic, inorganic, and organometallic species. (C) 2004 Elsevier B.V. All rights reserved.
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