Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 689, Issue 24, Pages 3939-3952Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2004.06.023
Keywords
organometallic photochemistry; carbonyl loss; metal metal bond homolysis; time resolved spectroscopy; matrix isolation
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The discovery of the light initiated reaction of Fe(CO)(5) to yield Fe-2(CO)(9) by Dewar and Jones in 1905 ushered in an era of the use of light to drive chemical reactions. This review seeks to examine selective chapters in this story by examining particularly significant reaction types in the context of their historical development. (C) 2004 Elsevier B.V. All rights reserved.
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