4.6 Article

Macroscopic ferroelectricity and piezoelectricity in nanostructured BiScO3-PbTiO3 ceramics

Journal

APPLIED PHYSICS LETTERS
Volume 94, Issue 1, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3056660

Keywords

bismuth compounds; ferroelectric Curie temperature; ferroelectric switching; ferroelectric transitions; lead compounds; nanostructured materials; piezoceramics; plasma materials processing; sintering

Funding

  1. MEC (Spain) [MAT2007-61884, MAT2008-02003/NAN]

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We have studied the macroscopic electrical properties of highly dense, nanostructured ceramics of BiScO3-PbTiO3 with high Curie temperature and piezoelectric activity. Materials were processed by spark plasma sintering of nanocrystalline powder obtained by mechanosynthesis. Results indicate that the nanostructured material still presents the ferroelectric transition above 700 K. Ferroelectric switching is unambiguously demonstrated. Furthermore, ceramic disks were poled and their radial piezoelectric resonance was excited, which has not been achieved in nanostructured BaTiO3 ceramics.

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