4.8 Article

Inelastic electron tunneling spectroscopy on decanethiol at elevated temoeratures

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Inelastic electron tunneling spectroscopy (IETS) measurements using scanning tunneling microscopy (STM) on a decanethiol self-assembled monolayer on Au(111) are presented. The results presented are obtained in the temperature range 77-300 K, which is a much higher temperature than what is commonly used for STM-IETS measurements. Two peaks at +/-34 meV (probably Au-S or S-C stretch mode) and +/-156 meV (C-C stretch mode or a CH2 mode) are resolved.

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