Journal
CATALYSIS LETTERS
Volume 98, Issue 4, Pages 229-233Publisher
KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1007/s10562-004-8685-y
Keywords
photocatalysis; overall water splitting; defect pyrochlore-type oxide; tungsten; conduction band
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Defect pyrochlore-type oxides, AMWO(6) (A = Rb, Cs; M = Nb, Ta), loaded with nickel oxide showed photocatalytic activity for overall water splitting under ultraviolet-light irradiation. The conduction bands of the materials are thought to be composed of the W5d orbital hybridized with the Nb5d or Ta4d orbital.
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