4.7 Article

Palladium-catalyzed Heck and carbonylation reactions of a dinaphthaleneiodonium salt formin functionalized 2-iodo-1,1′-binaphthyls

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 13-15, Pages 1728-1732

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404202

Keywords

binaphthyl; carbonylation; Heck reaction; iodonium salt; palladium catalyst

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The Heck-type olefination and carbonylation of a binaphthaleneiodonium salt 1 in the presence of a palladium catalyst gave high yields of the corresponding 2-iodo-2'-functionalized-1,1'-binaphthyls with high selectivity.

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