4.6 Article

Anomalies in the thermomechanical behavior of Ba0.5Sr0.5Co0.8Fe0.2O3-δ ceramic oxygen conductive membranes at intermediate temperatures

Journal

APPLIED PHYSICS LETTERS
Volume 95, Issue 5, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3193657

Keywords

barium compounds; ceramics; cobalt compounds; elastic constants; fracture; indentation; optical susceptibility; strontium compounds; thermomechanical treatment

Funding

  1. German Helmholtz Gemeinschaft [HA-104]

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The thermomechanical properties of Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) were measured using ring-on-ring tests and depth-sensitive microindentation. The cubic BSCF material exhibits an anomaly in mechanical properties between 200 and 400 degrees C. The observed anomaly is attributed to the transition of Co3+ spin states which is experimentally confirmed by susceptibility measurements. Furthermore, slip lines were observed around the impression when indentation tests were carried out above 260 degrees C.

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