Journal
ORGANIC ELECTRONICS
Volume 5, Issue 6, Pages 315-320Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.orgel.2004.10.005
Keywords
optical constants; optical ellipsometry; self-assembly; phenylene ethynylene oligomers
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This paper studies the self-assembly on gold surfaces of 1,4-ethynylphenyl-4'-ethynylphenyl-2'-nitro-1-benzenedithiolate (EP2NO(2)), a substituted phenylene ethynylene trimer with applications in molecular electronics. We develop an ellipsometric technique to measure the optical constants of these self-assembled monolayers, and we also use attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy and scanning tunneling microscopy (STM) to confirm the structure of the films. (C) 2004 Elsevier B.V. All rights reserved.
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