Journal
APPLIED PHYSICS LETTERS
Volume 95, Issue 14, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3247964
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The structure and energetics and the chemistry of graphene on SiO2 surface are studied from first-principles. It is found that the energetic preference for the graphene layer to bind on specific sites on the O-terminated surface differs substantially from that on the Si-terminated surface. Regardless of the location of binding sites on a particular surface, electrons transfer from the graphene layer to the dielectric surface and its quantity is higher for the O-terminated surface. In addition, the electron transfer strongly depends on the type of surface termination but is independent of the binding site. (C) 2009 American Institute of Physics. [doi:10.1063/1.3247964]
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