Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 13-15, Pages 1525-1532Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404223
Keywords
alkyl halides; C-C coupling; homogeneous; catalysis; nickel; synthetic methods
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Until recently, there had been a widespread perception that unactivated, beta-hydrogen-containing alkyl halides/pseudohalides are not suitable partners for nickel-catalyzed coupling reactions. During the past several years, a number of reports have dispelled this misconception by demonstrating that a diverse array of electrophiles and organometallic reagents can in fact be efficiently cross-coupled. 1 Introduction 2 Negisbi Couplings 2.1 Couplings of Primary Alkyl Halides 2.2 Couplings of Secondary Alkyl Halides 3 Suzuki Couplings of Primary and Secondary Alkyl Halides with Unsaturated Boronic Acids 4 Hiyama Couplings of Primary and Secondary Alkyl Halides with Trifluoroarylsilanes 5 Kumada Couplings of Primary Alkyl Halides and Tosylates with Grignard Reagents 6 Conclusions and Future Outlook
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