Journal
JOURNAL OF LUMINESCENCE
Volume 110, Issue 4, Pages 225-231Publisher
ELSEVIER
DOI: 10.1016/j.jlumin.2004.08.013
Keywords
oligothiophenes; cyclothiopbenes; Frenkel excitons; optical absorption
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We theoretically study the size-dependent relation between absorption spectra of thiophene-based oligomers and the corresponding cyclothiophenes. In our approach based on a Frenkel exciton Hamiltonian, we demonstrate that the geometry and selection rules determine the observed relations between the spectra. (C) 2004 Elsevier B.V. All rights reserved.
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