Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 13-15, Pages 1646-1650Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404148
Keywords
alkenylation; enolates; homogeneous catalysis; nitrogen heterocycles; palladium
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Vinyl halides undergo intramolecular coupling with amino-tethered ketones, esters, and nitriles in the presence of a palladium catalyst and potassium phenoxide as the base. This reaction constitutes a useful methodology for the synthesis of monocyclic, bridged, and spirocyclic nitrogen-containing compounds.
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