Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 13-15, Pages 1765-1772Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404145
Keywords
C-C coupling; cyclization; Heck reaction; homogeneous catalysis; rhodium
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Aroyl chlorides react with acyclic and cyclic alkenes in the presence of a rhodium catalyst to give Mizoroki-Heck type and cyclization products, respectively. A rhodium-ethylene complex, [{RhCI(C2H4)(2)}(2)], showed excellent performance for these reactions. Notably, the reactions can be conducted effectively under base- and phosphane-free conditions.
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