Journal
APPLIED PHYSICS LETTERS
Volume 92, Issue 3, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2832369
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Using first-principles methods, we investigate the effects of monatomic hydrogen in InN. We find that hydrogen can occupy interstitial and substitutional sites. Interstitial hydrogen is stable in the bond-center configuration and acts exclusively as a shallow donor, with a H-N stretching vibration at 3050 cm(-1). Hydrogen can also substitute for nitrogen in InN, bonding equally to the four In nearest neighbors in a multicenter-bond configuration. Substitutional hydrogen has low formation energy and, counterintuitively, is a double donor. Our results suggest that monatomic hydrogen is a plausible cause of the unintentional n-type conductivity that is often observed in as-grown InN. (c) 2008 American Institute of Physics.
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